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Microstructural characterization of Li insertion in individual silicon nanowires
- 作者:Gibaek Lee (1) (2)
Stefan L. Schweizer (2) Ralf B. Wehrspohn (1) (2)
- 刊名:Applied Physics A: Materials Science & Processing
- 出版年:2014
- 出版时间:November 2014
- 年:2014
- 卷:117
- 期:3
- 页码:973-979
- 全文大小:2,822 KB
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Stefan L. Schweizer (2) Ralf B. Wehrspohn (1) (2)
1. Fraunhofer Institute for Mechanics of Materials IWM, 06120, Halle (Saale), Germany 2. Department of Physics, Martin-Luther University, 06099, Halle (Saale), Germany
- ISSN:1432-0630
文摘
The lithiation and delithiation process of silicon nanowire arrays (SiNWs) on silicon substrates has been studied with high-resolution electron microscopy. The composition of lithiated SiNWs was revealed, consisting of the unreacted crystalline silicon core and the reacted amorphous Li–Si shell. In particular, the Li–Si shell was comprised of a mixture of amorphous silicon oxide and crystalline silicon, leading to hindrance during Li–Si alloying/dealloying upon cycling.
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