Synthesis and the crystal and molecular structure of the Sn(IV)–Nd(III) coordination polymer based on the tartaric acid [NdSn2{H(Tart)3} · 12H2O] n

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• 作者：V. S. Sergienko ; E. A. Chebanenko ; I. I. Seifullina…
• 刊名：Crystallography Reports
• 出版年：2016
• 出版时间：March 2016
• 年：2016
• 卷：61
• 期：2
• 页码：209-215
• 全文大小：494 KB
• 刊物类别：Physics and Astronomy
• 刊物主题：Physics
  Crystallography
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1562-689X
• 卷排序：61

文摘

The polymeric heterometallic [NdSn₂{H(Tart)₃} ∙ 12H₂O]_n (I) compound, where H₄Tart is the tartaric acid, is synthesized and characterized by elemental analysis, X-ray diffraction, thermogravimetry, and IR spectroscopy. The structural elements of crystal I, namely, polymeric [{Nd(H₂O)₆}(μ₃-H_nTart4–n) {Sn(μ₂-H_nTart4–n)}₂} (n = 0, 1) complex molecules and crystallization water molecules, are connected by an extended hydrogen-bond system.Original Russian Text © V.S. Sergienko, E.A. Chebanenko, I.I. Seifullina, A.V. Churakov, E.E. Martsinko, 2016, published in Kristallografiya, 2016, Vol. 61, No. 2, pp. 231–237.