Lattice Strain and Magnetic Property Evolution of La0.5Sr0.5Mn1↿em>x Co x

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Lattice Strain and Magnetic Property Evolution of La0.5Sr0.5Mn1↿em>x Co x

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作者：Wen Chen ; Yuye Chen ; Wenwei Wu ; Tangwei Li…
关键词：Manganites ; Chemical synthesis ; X ; ray diffraction ; Magnetic properties
刊名：Journal of Superconductivity Incorporating Novel Magnetism
出版年：2016
出版时间：January 2016
年：2016
卷：29
期：1
页码：115-122
全文大小：958 KB
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作者单位：Wen Chen (1)
Yuye Chen (1)
Wenwei Wu (1) (2)
Tangwei Li (1)
Cuiyan Zhang (1)
Yuan Zhou (1)
Juan Wu (1)

1. School of Chemistry and Chemical Engineering, Guangxi University, Nanning, 530004, People’s Republic of China
2. Guangxi Colleges and Universities Key Laboratory of Applied Chemistry Technology and Resource Development, Nanning, 530004, People’s Republic of China
刊物类别：Physics and Astronomy
刊物主题：Physics
Superconductivity, Superfluidity and Quantum Fluids
Magnetism and Magnetic Materials
Condensed Matter
Characterization and Evaluation Materials
出版者：Springer New York
ISSN：1557-1947

文摘

La_0.5Sr_0.5Mn_1−xCo_x O ₃ (0 ≤x ≤ 0.3) is obtained by calcining the precursor carbonates in air. The precursor and its calcined products are characterized by X-ray powder diffraction, scanning electron microscopy, and vibrating sample magnetometer. A highly crystallized La _0.5Sr _0.5Mn _1−xCo _x O ₃ (0 ≤x ≤ 0.3) with a perovskite structure is obtained when the precursor is calcined at 900 ∘C in air for 3 h. The lattice strains of La _0.5Sr _0.5Mn _1−xCo _x O ₃ increase with the increase of Co content and/or the decrease of Mn content between x = 0 and x = 0.1 at first, then decreases with the increase of Co content. The magnetic properties of La _0.5Sr _0.5Mn _1−xCo _x O ₃ depend on the composition and measurement temperature. Cobalt substitution can markedly improve the coercivity of La _0.5Sr _0.5Mn _1−xCo _x O ₃.