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Hydrothermal synthesis of tin containing mesoporous silicas and their catalytic performance over Baeyer–Villiger oxidation of cyclohexanone to ε-caprolactone: comparison of Sn/MCM-41 and Sn/SBA-15
- 作者:Tian Chen ; Bendong Wang ; Yongchao Li ; Lei Liu ; Shufan Qiu
- 关键词:SBA ; 15 ; MCM ; 41 ; Baeyer–Villiger oxidation ; Cyclohexanone ; ε ; Caprolactone
- 刊名:Journal of Porous Materials
- 出版年:2015
- 出版时间:August 2015
- 年:2015
- 卷:22
- 期:4
- 页码:949-957
- 全文大小:883 KB
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- 作者单位:Tian Chen (1)
Bendong Wang (1) Yongchao Li (1) Lei Liu (1) Shufan Qiu (1)
1. College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, 210016, China
- 刊物类别:Chemistry and Materials Science
- 刊物主题:Chemistry
Catalysis Characterization and Evaluation Materials Physical Chemistry
- 出版者:Springer Netherlands
- ISSN:1573-4854
文摘
In this work, a series of tin containing mesoporous silicas (Sn/MCM-41 and Sn/SBA-15) were prepared by a one-pot hydrothermal method and their physical and chemical properties were characterized by various techniques such as powder X-ray diffraction, nitrogen adsorption–desorption and transmission electron microscopy. Among these catalysts, Sn/SBA-15(50) exhibited the highest catalytic activity for Baeyer–Villiger oxidation of cyclohexanone to ε-crolactone using hydrogen peroxide (H2O2) as the green oxidant. The best methodology was to carry out the reaction in 1,4-dioxane under 10?wt% Sn/SBA-15 catalyst of 0.1?mol cyclohexanone at 70?°C for 4?h, and a molar ratio cyclohexanone: oxidant of 1:3. Furthermore, this heterogeneous mesoporous Sn/SBA-15 catalyst was reusable without any appreciable loss in activity and selectivity after three cycles.
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