Iridium-catalyzed cascade dehydrogenation, ring-closure reaction leading to 2,4,6-triaryl-1,3,5-triazines

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• 作者：Gang Shi ; Fei He ; Youxin Che ; Caihua Ni ; Ying Li
• 关键词：iridium catalysis ; ring ; closure reaction ; dehydrogenation ; 2 ; 4 ; 6 ; triaryl ; 1 ; 3 ; 5 ; triazines
• 刊名：Russian Journal of General Chemistry
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：86
• 期：2
• 页码：380-386
• 全文大小：209 KB
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• 作者单位：Gang Shi (1)
  Fei He (1)
  Youxin Che (1)
  Caihua Ni (1)
  Ying Li (1) (2)
  
  1. The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu Province, 214122, China
  2. National Engineering Laboratory for Cereal Fermentation Technology, Jiangnan University, Wuxi, Jiangsu Province, 214122, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Chemistry
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1608-3350

文摘

An efficient iridium-catalyzed dehydrogenation, ring-closure reaction, has been developed via a cascade sequence, in which [Cp*IrI₂]₂/Xantphos proved to be the most efficient catalyst for the synthesis of 2,4,6-triaryl-1,3,5-triazines from stable aryl-substituted alcohols and amidines. It was the first case of iridium catalyst successful application in such transformation.