New bimodal pore catalysts for Fischer–Tropsch synthesis

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• 作者：Shinoda ; Misao ; Zhang ; Yi ; Yoneyama ; Yoshiharu ; Hasegawa ; Kiyoshi ; Tsubaki ; Noritatsu
• 关键词：Bimodal pore support ; Fischer&ndash ; Tropsch synthesis (FTS) ; Syngas ; Cobalt catalyst ; Zirconia
• 刊名：Fuel Processing Technology
• 出版年：2004
• 期刊代码：36_03783820
• 类别：ce
• 出版时间：November 15, 2004
• 卷：86
• 期：1
• 页码：73-85
• 文件大小：293 K

摘要

A simple preparation method of bimodal pore supports was developed by introducing SiO₂ or ZrO₂ sols into large pores of SiO₂ gel pellets directly. The pores of the obtained bimodal pore supports distributed distinctly as two kinds of main pores. On the other hand, the increased BET surface area and decreased pore volume, compared to those of original silica gel, indicated that the obtained bimodal pore supports formed according to the designed route. The obtained bimodal pore supports were applied in liquid-phase Fischer–Tropsch synthesis (FTS) where cobalt was supported. The bimodal pore catalysts presented the best reaction performance in liquid-phase Fischer–Tropsch synthesis (FTS) as higher reaction rate and lower methane selectivities, because the spatial promotional effect of bimodal pore structure and chemical effect of the porous zirconia behaved inside the large pores of original silica gel.