稀土Pr对Sn-Cu合金钎料组织及性能的影响
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  • 英文篇名:Effect of Rare Earch Pr on Microstructure and Properties of Sn-Cu Solder
  • 作者:廖春丽
  • 英文作者:LIAO Chunli;Nanchong Institute of Technology;
  • 关键词:稀土Pr ; Sn-0.7Cu ; 润湿性能 ; 拉伸性能 ; 蠕变性能 ; 三元共晶
  • 英文关键词:rare earth Pr;;Sn-0.7Cu;;wettability;;tensile properties;;creep properties;;ternary eutectic
  • 中文刊名:SJGY
  • 英文刊名:Hot Working Technology
  • 机构:南充职业技术学院;
  • 出版日期:2019-01-16 11:14
  • 出版单位:热加工工艺
  • 年:2019
  • 期:v.48;No.503
  • 基金:四川省教育厅自然科学基金项目(No.16ZB0465)
  • 语种:中文;
  • 页:SJGY201901058
  • 页数:4
  • CN:01
  • ISSN:61-1133/TG
  • 分类号:214-216+220
摘要
研究了含量为(0wt%,0.1wt%,0.2wt%,0.5wt%)的稀土Pr对Sn-0.7Cu钎料组织及性能的影响,并采用X射线衍射仪和扫描电镜对添加Pr稀土元素前后钎料的微观组织进行了分析。结果表明:适量添加稀土Pr可以降低液态钎料表面张力,改善钎料的润湿性能、拉伸性能和蠕变性能;适量的稀土元素与Sn、Cu形成的Sn-Cu-Pr三元共晶组织减少了金属间化合物Cu_6Sn_5的生成,且其与Cu_6Sn_5呈弥散分布,对基体组织起到了细晶强化和弥散强化的作用。Pr在Sn-0.7Cu钎料中的最佳添加量为0.1wt%左右。
        The effect of rare earth Pr(0wt %, 0.1wt %, 0.2wt %, 0.5wt %) on the microstructure and properties of Sn-0.7Cu solder was investigated. The microstructure of Sn-0.7 Cu brazing filler metals with and without the addition of Pr was analyzed by using X-ray diffractometer and scanning electron microscopy. The results show that proper amount of rare earth Pr can reduce the surface tension of the liquid solder, improve the wettability of the filler, tensile properties and creep properties. The Sn-Cu-Pr ternary eutectic structure formed by proper amount of rare earth elements and Sn, Cu reduces the formation of intermetallic compound Cu_6Sn_5, and they are distributed uniformly, which plays the role of fine crystal strengthening and dispersion strengthening on the matrix structure. The optimum addition of Pr in Sn-0.7Cu solder is about 0.1wt%.
引文
[1] Yoon J W, Lee Y H, Kim D G, et al. Intermetallic compound layer growth at the interface between Sn-Cu-Ni solder and Cu substrate[J]. Journal of Alloys and Compounds, 2004, 381(1/2):151-157.
    [2] IslamM N, Chan Y C. Interfacial reactions of Sn-Cu solder with Ni/Au surface finish on Cu pad during reflow and aging in ball grid array packages[J].Materials Science and Engineering B,2005,117(1):246-253.
    [3] Gourlay CM, Nogita K,Mc Donald S D,et al. A rheological assessment of the effect of trace level Ni additions on the solidification of Sn-0.7Cu[J].Scrip ta Materialia, 2006,54(9):1557-1562.
    [4] Wu C M L,Law C M T,Yu D Q,et al.The wettability and microstructure of Sn-Zn-RE alloys[J].Journal of Electronic Materials,2003,32(2):63-69.
    [5]刘顺华,王桂芹,吴爱民等.稀土元素对工业纯铝导电性的影响[J].中国有色金属学报,2000,10(3):334-335
    [6]廖春丽.Sn-0.7Cu-1Ag无铅钎料压入蠕变行为的研究[J].铸造技术,2013,34(3):256-257
    [7] Zhang L,Xue S B,Gao L L, et al.Effects of trace amount addition of rare earth on properties and microstructure of Sn-Ag-Cu alloys[J].Journal of Materials Science:Materials in Electronics,2009,20(12):1193-1199.
    [8] Yuan G Y, Liu M P, Ding W J, et al.Microstructure and mechanical properties of Mg-Zn-Si based alloys[J].Materials Science and Engineering A,2003, 357:314-320.
    [9] Yu D Q, Zhao J, Wang L. Improvement on the microstructure stability, mechanical and wetting properties of Sn-Ag-Cu lead-free solder with the addition of rare earth elements[J].Journal of Alloys and Compounds, 2004, 376(1/2):170-175.
    [10] Wang J X, Xue S B, Han Z J, et al. Effects of rare earth Ce on microstructures, solderability of Sn-Ag-Cu and Sn-Cu-Ni solders as well as mechanical properties of soldered joints[J]. Journal of Alloys and Compounds, 2009, 467(1/2):219-226.
    [11] Shi Y W, Tian J, Hao H, et al. Effects of small amount addition of rare earth Er on microstructure and property of Sn Ag Cu solder[J]. Journal of Alloys and Compounds, 2008,453(1/2):180-184.
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