高分辨质谱在氯化石蜡分析方法中的应用

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英文篇名：Applications of High-Resolution Mass Spectrometry in Determination of Chlorinated Paraffins 作者：黄晓梅 ; 吴杨 ; 崔君涛 ; 王富华 ; 王旭 ; 李亚菲 ; 吴维煇 英文作者：HUANG Xiao-Mei;WU Yang;CUI Jun-Tao;WANG Fu-Hua;WANG Xu;LI Ya-Fei;WU Wei-Yun;Public Monitoring Center for Agro-product of Guangdong Academy of Agricultural Sciences;Laboratory of Quality & Safety Risk Assessment for Agro-products (Guangzhou),Ministry of Agriculture and Rural Affairs;State Key Laboratory of Organic Geochemistry,Guangdong Provincial Key Laboratory of Utilization and Protection of Environmental Resources,Guangzhou Institute of Geochemistry,Chinese Academy of Sciences;University of Chinese Academy of Sciences; 关键词：氯化石蜡 ; 四极杆飞行时间高分辨质谱 ; 轨道离子阱高分辨质谱 ; 气相色谱 ; 液相色谱 ; 评述 英文关键词：Chlorinated paraffins;;Quadrupole time-of-flight high-resolution mass spectrometry;;Orbitrap high-resolution mass spectrometry;;Gas chromatography;;Liquid chromatography;;Review 中文刊名：FXHX 英文刊名：Chinese Journal of Analytical Chemistry 机构：广东省农业科学院农产品公共监测中心;农业农村部农产品质量安全风险评估实验室(广州);中国科学院广州地球化学研究所有机地球化学国家重点实验室广东省环境资源利用与保护重点实验室;中国科学院大学; 出版日期：2019-03-07 出版单位：分析化学 年：2019 期：v.47 基金：国家自然科学科学基金项目(No.41807380);; 广东省标准化研究项目(No.粤财农[2016]310号);; 广东省农业科学院科技人才引进专项资金项目(No.粤农科人[2018]3号);广东省农业科学院新兴学科团队建设项目(No.201804XX)资助 supported by the National Natural Science Foundation of China(No.41807380);; the Standardization Research Project of Guangdong Province,China(Guangdong Finance and Agriculture [2016] No.310);; the Special Talent Projects in Guangdong Academy of Agricultural Sciences(Guangdong Agriculture Sciences Talents [2018] No.3)and the New Discipline Team Project in Guangdong Academy of Agricultural Sciences(No.201804XX) 语种：中文; 页：FXHX201903001 页数：12 CN：03 ISSN：22-1125/O6 分类号：10-21

摘要

氯化石蜡(CPs)是一类新型持久性有机污染物,也是我国环境介质和生物体污染最严重的卤代有机污染物(OHPs)之一,近年来引起研究者高度关注。由于环境样品基质较为复杂,且其中CPs的含量水平相对较低,CPs需经提取与净化后才能进行仪器检测。CPs的同系物和异构体多达数千种,消除CPs单体以及其它OHPs的质量干扰是仪器检测CPs的关键。高分辨质谱(HRMS)具有相对较高的分辨率,能够解决这一关键问题。本文介绍了环境样品中CPs的提取与净化方法,主要从气相色谱-高分辨质谱(GC-HRMS)和液相色谱-高分辨质谱(LC-HRMS)两个方面阐述HRMS在CPs分析中应用的研究进展,总结了目前CPs分析方法中存在的问题,并对未来的发展趋势进行了展望。
        Chlorinated paraffins (CPs) are a new class of persistent organic pollutants and have aroused great concern of many environmental scientists due to their ubiquity in various environmental media and biotas.Given their relative low levels in environmental samples,CPs need to be enriched and cleaned up before instrumental analysis. CPs consist of thousands of congeners and isomers,thus posing grand challenges to eliminate the mass interference by homologues and other organohalogen compounds during instrumental examination. Fortunately,high-resolution mass spectrometry (HRMS) owns the powerful ability to solve this key problem owing to its high mass resolution. This review introduced the methods of pretreatment and instrumental analysis of CPs-containing samples in the environment,mainly illustrating the application of gas chromatography and liquid chromatography coupled with HRMS (i.e. GC-HRMS and LC-HRMS). The existing issues and prospects of future study were also discussed.

引文

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