摘要
二氧化钒(VO2)具有优异的半导体-金属相变特性,具有良好的应用前景。由于二氧化钒纳米粉体的表面效应,它们常易团聚,使得它在应用中受到很大的局限性,这就需要对纳米二氧化钒粉体进行表面改性。综述了对纳米二氧化钒粉体进行改性处理的方法,介绍了二氧化钒的应用研究新进展,并展望了二氧化钒涂层在智能窗方面的应用中遇到的问题和应用新方向。
Vanadium dioxide(VO2)is one of the metal-semiconductor phase transition,materials with good prospects.Therefore,vanadium dioxide has good application prospect.Due to surface effects of vanadium dioxide nanopowders,which often easy reunion and makes it subject to significant limitations in the application,it requires surface modification of nanopowders of vanadium dioxide.Modified approach of vanadium dioxide nanopowders and the application new progress of vanadium dioxide are described.Finally,the problem of VO2 coating in the applications of smart windows and a new direction in application are prospected.
引文
1 Morin F J.Oxide which show a metal-insulator transition at the neel temperature[J].Phys Rev Lett,1959,13(1):34
2 Chae B G,Youn D H,Kim H T,et al.Fabrication and electrical properties of pure VO2 phase films[J].J Korean Phys Soc,2004,44(4):884
3 Bialas H,Dillenz A,Downar H,et al.Epitaxial relationships and electrical properties of vanadium oxide films on rcut sapphire[J].Thin Solid Films,1999,338:60
4 Schlag H J,Scherber W.New sputter process for VO2thin films and examination with MIS-elements and C-V-measurements[J].Thin Solid Films,2000,366:28
5 Jiang M,Bao S,Cao X,et al.Improved luminous transmittance and diminished yellow color in VO2 energy efficient smart thin films by Zn doping[J].Ceram Int,2014,40:6331
6 Chen B,Yang D B,Charpentiera P A,et al.Al 3+-doped vanadium dioxide thin films deposited by PLD[J].Solar Energy Mater Solar Cells,2009,93(9):1550
7 Paonea A,et al.Influence of doping in thermochromic V1-xWxO2and V1-xAlxO2thin films:Twice improved doping efficiency in V1-xWxO2[J].J Alloys Compd,2015,621:206
8 Pergament A Stefanovich,et al.Electrical conductivity of tungsten doped vanadium dioxide obtained by the sol-gel technique[J].Thin Solid Films,2013,531:572
9 Kiri P,Warwick M E A,et al.Fluorine doped vanadium dioxide thin films for smart windows[J].Thin Solid Films,2011,520(4):1363
10 张华,肖秀娣,徐刚,等.二氧化钒薄膜的研究进展[J].材料导报:综述篇,2014,28(7):56
11 Xu B S.Nano-surface engineering[M].Beijing:Chemical Industry Press,2004
12 周瑞发,韩丫芳,陈祥宝.纳米材料技术[M].北京:国防工业出版社,2003
13 彭子飞.一种二氧化钒悬浮液的制备方法:中国,2006101170274[P].2007-03-28
14 Li R,Ji S D,Li Y M,et al.Synthesis and characterization of plate-like VO2(M)@SiO2nanoparticles and their application to smart window[J].Mater Lett,2013,110:241
15 Gao Y F,Wang S B,Luo H J,et al.Enhanced chemical stability of VO2nanoparticles by the formation of SiO2/VO2core/shell structures and the application to transparent and flexible VO2-based composite foils with excellent thermochromic properties for solar heat control[J].Energy Environmental Sci,2012,3:6104
16 Zhang Y F,Fan M J,Wu W B,et al.A novel route to fabricate belt-like VO2(M)@C core-shell structured composite and its phase transition properties[J].Mater Lett,2012,71:127
17 Zhang Y F,Liu X H,Xie G Y,et al.Hydrothermal synthesis,characterization,formation mechanism and electrochemical property of V3O7·H2O single-crystal nanobelts[J].Mater Sci Eng B,2010,175(2):64
18 Zhang Y F,Zhou M,Fan M J,et al.Improvement of the electrochemical properties of V3O7·H2O nanobelts for Li battery application through synthesis of V3O7@C core-shell nanostructured composites[J].Current Appl Phys,2011,11:1159
19 Zhang Y F,Liu X H,Chen D Z,et al.Fabrication of V3O7·H2O@C core-shell nanostructured composites and the effect of V3O7·H2O and V3O7·H2O@C on decomposition of ammonium perchlorate[J].J Alloys Compd,2011,509(5):69
20李志杰.一种金属离子改性的二氧化钒花状粉末材料的制备方法:中国,2012103635661[P].2012-09-27
21 罗宏杰.一种二氧化钒智能温控涂层:中国,2012100179385[P].2013-05-01
22 Chen Y,Su Z X,Xu H.The preparation and characterization of surface-modified VO2 nanopowders[J].Synthesis Reactivity Inorg Metal-Organic Nano-Metal Chem,2007,37(4):275
23 宋铿.二氧化钒智能控温材料的制备及性能研究[D].大连:大连理工大学,2011
24 周莉.掺杂立氧化钒超细粉体的制备及性能研究[D].大连:大连理工大学,2010
25 齐济,宁桂玲,刘俊龙,等.二氧化钒粉体研究的新进展[J].化工进展,2010,29(8):1513
26 Zheng J Y,Bao S H,Jin P.TiO2(R)/VO2(M)/TiO2(A)multilayer film as smart window:Combination of energysaving,antifogging and self-cleaning functions[J].Nano Energy,2015,11:136
27 Li W J,Ji S D,Qian K,et al.Preparation and characterization of VO2-BaSO4 composite films with enhanced optical propertiesin thermochromic field[J].Ceram Int,2015,41(3):5049
28 Chen Z,Gao Y F,Kang L T,et al.VO2-based double-layered films for smart windows:Optical design,all-solution preparation and improved properties[J].Solar Energy Mater Solar Cells,2011,95:2677
29 黄维刚,林华,涂铭旌.纳米VO2粉体的制备及性能和应用[J].表面技术,2004,33(1):67
30 Choi S B,Kyoung S J,Kim H S.Nanopattern enabled terahertz all-optical switching on vanadium dioxide thin film[J].Appl Phys Lett,2011,98(7):1105
31 Crunteanu A,Leroy J,Humbert G,et al.Tunable terahertz metamaterials based on metal-insulator phase transition of VO2layers[C]//Microwave Symposium Digest(MTT),2012IEEE MTT-S International.Motroal,Canada,2012
32 Sun Y,Yang S B,Lv L P,et al.A composite film of reduced graphene oxide modified vanadium oxide nanoribbons as a free standing cathode material for rechargeable lithium batteries[J].J Power Sources,2013,241:168
33 Wang Q,Pan J,Li M,et al.VO2(B)nanosheets as a cathode material for Li-ion battery[J].J Mater Sci Technol,2015,31(6):630
34 杨培志,刘黎明,莫镜辉.微测辐射热计用VO2薄膜及其改性研究[J].云南师范大学学报,2011,31(3):26
35 康晓春,赵颖,王胤博,等.二氧化钒制备与应用的新进展[J].材料导报,2008,22(专辑Ⅻ):196
36 Mlyuka N R,Niklasson G A,Granqvist C G.Thermochromic multi-layer films of VO2and TiO2with enhanced transmittance[J].Solar Energy Mater Solar Cells,2009,93:1685