Using trace elements of magnetite to constrain the origin of the Pingchuan hydrothermal low-Ti magnetite deposit in the Panxi area, SW China
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  • 英文篇名:Using trace elements of magnetite to constrain the origin of the Pingchuan hydrothermal low-Ti magnetite deposit in the Panxi area, SW China
  • 作者:Yanjun ; Wang ; Weiguang ; Zhu ; Hong ; Zhong ; Zhongjie ; Bai ; Junhua ; Yao ; Chong ; Xu
  • 英文作者:Yanjun Wang;Weiguang Zhu;Hong Zhong;Zhongjie Bai;Junhua Yao;Chong Xu;State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences;University of Chinese Academy of Sciences;
  • 英文关键词:SW China;;Pingchuan iron deposit;;Low-Ti iron deposit;;Hydrothermal magnetite
  • 中文刊名:DQHB
  • 英文刊名:地球化学学报(英文版)
  • 机构:State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences;University of Chinese Academy of Sciences;
  • 出版日期:2019-05-17
  • 出版单位:Acta Geochimica
  • 年:2019
  • 期:v.38
  • 基金:supported by the National Natural Science Foundation of China (Grants 41572074 and 41273049);; the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDB18030204)
  • 语种:英文;
  • 页:DQHB201903005
  • 页数:15
  • CN:03
  • ISSN:52-1161/P
  • 分类号:52-66
摘要
The Pingchuan iron deposit, located in the Yanyuan region of Sichuan Province, SW China, has an ore reserve of 40 Mt with ~60 wt% Fe. Its genesis is still poorly understood. The Pingchuan iron deposit has a paragenetic sequence of an early Fe-oxide–Pyrite stage(Ⅰ) and a late Fe-oxide–pyrrhotite stage(Ⅱ). Stage Ⅰ magnetite grains are generally fragmented, euhedral–subhedral, largesized crystals accompanying with slightly postdated pyrite.Stage Ⅱ magnetite grains are mostly unfragmented, anhedral, relatively small-sized grains that co-exist with pyrrhotite. Combined with micro-textural features and previously-obtained geochronological data, we consider that these two stages of iron mineralization in the Pingchuan deposit correspond to the Permian ELIP magmatism and Cenozoic fault activity event. Both the Stage Ⅰ and Ⅱ magnetites are characterized with overall lower contents of trace elements(including Cr, Ti, V, and Ni) than the ELIP magmatic magnetite, which suggests a hydrothermal origin for them. ‘‘Skarn-like'' enrichment in Sn, Mn, and Zn in the Stage Ⅰ magnetite grains indicate significant material contributions from carbonate wall-rocks due to water–rock interaction in ore-forming processes. Stage Ⅱ magnetite grains contain higher Mn concentrations than Stage Ⅰ magnetite grains, which possibly implies more contribution from carbonate rocks. In multiple-element diagrams, the Stage Ⅰ magnetite shows systematic similarities to Kiruna-type magnetite rather than those from other types of deposits. Combined with geological features and previous studies on oxygen isotopes, we conclude that hydrothermal fluids have played a key role in the generation of the Pingchuan low-Ti iron deposit.
        The Pingchuan iron deposit, located in the Yanyuan region of Sichuan Province, SW China, has an ore reserve of 40 Mt with ~60 wt% Fe. Its genesis is still poorly understood. The Pingchuan iron deposit has a paragenetic sequence of an early Fe-oxide–Pyrite stage(Ⅰ) and a late Fe-oxide–pyrrhotite stage(Ⅱ). Stage Ⅰ magnetite grains are generally fragmented, euhedral–subhedral, largesized crystals accompanying with slightly postdated pyrite.Stage Ⅱ magnetite grains are mostly unfragmented, anhedral, relatively small-sized grains that co-exist with pyrrhotite. Combined with micro-textural features and previously-obtained geochronological data, we consider that these two stages of iron mineralization in the Pingchuan deposit correspond to the Permian ELIP magmatism and Cenozoic fault activity event. Both the Stage Ⅰ and Ⅱ magnetites are characterized with overall lower contents of trace elements(including Cr, Ti, V, and Ni) than the ELIP magmatic magnetite, which suggests a hydrothermal origin for them. ‘‘Skarn-like'' enrichment in Sn, Mn, and Zn in the Stage Ⅰ magnetite grains indicate significant material contributions from carbonate wall-rocks due to water–rock interaction in ore-forming processes. Stage Ⅱ magnetite grains contain higher Mn concentrations than Stage Ⅰ magnetite grains, which possibly implies more contribution from carbonate rocks. In multiple-element diagrams, the Stage Ⅰ magnetite shows systematic similarities to Kiruna-type magnetite rather than those from other types of deposits. Combined with geological features and previous studies on oxygen isotopes, we conclude that hydrothermal fluids have played a key role in the generation of the Pingchuan low-Ti iron deposit.
引文
Ali JR,Thompson GM,Zhou MF,Song XY(2005)Emeishan large igneous province,SW China.Lithos 79:475-489
    Bai ZJ,Zhong H,Li C,Zhu WG,Xu GW(2012a)Platinum-group elements in the oxide layers of the Hongge mafic-ultramafic intrusion,Emeishan Large Igneous Province,SW China.Ore Geol Rev 46:149-161
    Bai ZJ,Zhong H,Naldrett AJ,Zhu WG,Xu GW(2012b)Whole-rock and mineral composition constraints on the genesis of the giant Hongge Fe-Ti-V oxide deposit in the Emeishan Large Igneous Province,Southwest China.Econ Geol 107:507-524
    Broughm SG,Hanchar JM,Tornos F,Westhues A,Attersley S(2017)Mineral chemistry of magnetite from magnetite-apatite mineralization and their host rocks:examples from Kiruna,Sweden,and El Laco,Chile.Miner Depos 52:1223-1244
    Carew MJ(2004)Controls on Cu-Au mineralization and Fe oxide metasomatism in the Eastern Fold Belt,N.W.Queensland,Australia.Ph.D thesis,James Cook University,Queensland
    Chen LM,Song XY,Zhu XK,Zhang XQ,Yu SY,Yi JN(2014)Iron isotope fractionation during crystallization and sub-solidus reequilibration:constraints from the Baima mafic layered intrusion,SW China.Chem Geol 380:97-109
    Chung SL,Jahn BM(1995)Plume-lithosphere interaction in generation of the Emeishan flood basalts at the Permian-Triassic boundary.Geology 23:889-892
    Dare SAS,Barnes SJ,Beaudoin G,Meric J,Boutroy E,PotvinDoucet C(2014)Trace elements in magnetite as petrogenetic indicators.Miner Depos 49:785-796
    Dupuis C,Beaudoin G(2011)Discriminant diagrams for iron oxide trace element fingerprinting of mineral deposit types.Miner Depos 46:319-335
    Einaudi MT,Hedenquist JW,Inan EE(2003)Sulfidation state of fluids in active and extinct hydrothermal systems:transitions from porphyry to epithermal environments.Soc Econ Geol Spec Publ 10:285-313
    Gao JF,Zhou MF,Lightfoot PC,Wang CY,Qi L,Sun M(2013)Sulfide saturation and magma emplacement in the formation of the Permian Huangshandong Ni-Cu sulfide deposit,Xinjiang,northwestern China.Econ Geol 108:1833-1848
    Ge XH(1984)A discussion on nappe structure in Yanyuan,west Sichuan.J Jilin Univ(Earth Sci Ed)1:36-43(in Chinese with English abstract)
    Hou T,Charlier B,Holtz F,Veskler I,Zhang ZC,Thomas R,Namur O(2018)Immiscible hydrous Fe-Ca-P melt and the origin of iron oxide-apatite ore deposits.Nat Commun 9:1415
    Knipping JL,Bilenker LD,Simon AC,Reich M,Barra F,Deditius AP,Lundstrom C,Bindeman I,Munizaga R(2015a)Giant Kiruna-type deposits form by efficient flotation of magmatic magnetite suspensions.Geology 43:591-594
    Knipping JL,Bilenker LD,Simon AC,Reich M,Barra F,Deditius AP,Wa¨lle M,Heinrich CA,Holtz F,Munizaga R(2015b)Trace elements in magnetite from massive iron oxide-apatite deposits indicate a combined formation by igneous and magmatichydrothermal processes.Geochim Cosmochim Acta 171:15-38
    Li ZX,Li XH,Kinny PD,Wang J,Zhang S,Zhou H(2003)Geochronology of Neoproterozoic syn-rift magmatism in the Yangtze Craton,South China and correlations with other continents:evidence for a mantle superplume that broke up Rodinia.Precambrian Res 122:85-109
    Li XH,Li ZX,Sinclair JA,Li WX,Carter G(2006)Revisiting the‘‘Yanbian Terrane’’:implications for Neoproterozoic tectonic evolution of the western Yangtze Block,South China.Precambrian Res 151:14-30
    Liu YS,Hu ZC,Gao S,Gunther D,Xu J,Gao CG,Chen HH(2008)In situ analysis of major and trace elements of anhydrous minerals by LA-ICP-MS without applying an internal standard.Chem Geol 257:34-43
    Liu PP,Zhou MF,Chen WT,Gao JF,Huang XW(2015a)In-situ LA-ICP-MS trace elemental analyses of magnetite:Fe-Ti-(V)oxide-bearing mafic-ultramafic layered intrusions of the Emeishan Large Igneous Province,SW China.Ore Geol Rev 65:853-871
    Liu WH,Zhang J,Sun T,Zhou L,Liu AL(2015b)Low-Ti iron oxide deposits in the Emeishan large igneous province related to lowTi basalts and gabbroic intrusions.Ore Geol Rev 65:180-197
    Ma Y,Ji XT,Li JC,Huang M,Kan ZZ(2003)Mineral resources of the Panzhihua region.Sichuan Science and Technology Press,Chengdu,p 275(in Chinese)
    Nadoll P,Angerer T,Mauk JL,French D,Walshe J(2014)The chemistry of hydrothermal magnetite:a review.Ore Geol Rev61:1-32
    Nadoll P,Mauk JL,Leveille RA,Koenig AE(2015)Geochemistry of magnetite from porphyry Cu and skarn deposits in the southwestern United States.Miner Depos 50:493-515
    Panxi Geological Team(1982)Detailed geological prospecting report of Kungshangliangzi iron ore in Yanyuan country,Sichuan province.Unpublished p 25(in Chinese)
    Rudnick R,Gao S(2003)Composition of the continental crust.Treatise Geochem 3:1-64
    SBGMR(Sichuan Bureau of Geology and Mineral Resources)(1991)Regional geology of Sichuan province.Geological Publishing House,Beijing,p 680(in Chinese)
    Shellnutt JG,Denyszyn SW,Mundil R(2012)Precise age determination of mafic and felsic intrusive rocks from the Permian Emeishan Large Igneous Province(SW China).Gondwana Res22:118-126
    Song XY,Zhang CJ,Hu RZ,Zhong H,Zhou MF,Ma RZ,Li YG(2005)Genetic links of magmatic deposits in the Emeishan large igneous province with dynamics of mantle plume.J Mineral Petrol 25(4):35-44(in Chinese with English abstract)
    Song XY,Keays RR,Xiao L,Qi HW,Ihlenfeld C(2009)Platinumgroup element geochemistry of the continental flood basalts in the central Emeisihan Large Igneous Province,SW China.Chem Geol 262:246-261
    Song XY,Qi HW,Hu RZ,Chen LM,Yu SY,Zhang JF(2013)Formation of thick stratiform Fe-Ti oxide layers in layered intrusion and frequent replenishment of fractionated mafic magma:evidence from the Panzhihua intrusion,SW China.Geochem Geophys Geosyst 14:712-732
    Wang M,Zhang ZC,Encarnacion J,Hou T,Luo WJ(2012)Geochronology and geochemistry of the Nantianwan maficultramafic complex,Emeishan large igneous province:metallogenesis of magmatic Ni-Cu sulphide deposits and geodynamic setting.Int Geol Rev 54:1746-1764
    Wang M,Zhang ZC,Santosh M,Hou T(2014)Geochemistry of Late Permian picritic porphyries and associated Pingchuan iron ores,Emeishan Large Igneous Province,Southwest China:constraints on petrogenesis and iron sources.Ore Geol Rev 57:602-617
    Wang YC,Gao JF,Huang XW,Qi L,Lyu C(2018)Trace element composition of magnetite from the Xinqiao Fe-S(-Cu-Au)deposit,Tongling,Eastern China:constraints on fluid evolution and ore genesis.Acta Geochim 37(5):639-654
    Yang SH(1983)Approach to character and genesis of magnetite from Kuangshanliangzi magnetite deposit,Yanyuan,Sichuan.Bull Chengdu Inst Geol M R Chin Acad Geol Sci 4:33-43(in Chinese with English abstract)
    Yao ZD,Yan YQ(1991)A further understanding on genesis of the Kuangshanliangzi-Niuchang magnetite deposits in Yanyuan region,Sichuan Province.Acta Geol Sichuan 11(2):117-126(in Chinese)
    Zeng LG,Zhang J,Sun T,Guo DB(2013)Zircon U-Pb age of maficultramafic rock from Pingchuan region in Southern Sichuan and its geological implications.Earth Sci J China Univ Geosci38(6):1197-1213(in Chinese with English abstract)
    Zhang ZC,Mahoney JJ,Mao JW,Wang FS(2006)Geochemistry of picritic and associated basalt flows of the western Emeishan flood basalt province,China.J Petrol 47:1997-2019
    Zhao WW,Zhou MF(2015)In-situ LA-ICP-MS trace elemental analyses of magnetite:the Mesozoic Tengtie skarn Fe deposit in the Nanling Range,South China.Ore Geol Rev 65:872-883
    Zhong KH,Liu ZC,Shi YS,Li FY,Shu LS(2004)Yanyuan-Lijiang tectonic zone:a Cenozoic intracontinental orogenic belt.Acta Geol Sin 78(1):36-43(in Chinese with English abstract)
    Zhong H,Qi L,Hu RZ,Zhou MF,Gou TZ,Zhu WG,Liu BG,Chu ZY(2011)Rhenium-osmium isotope and platinum-group elements in the Xinjie layered intrusion,SW China:Implications for source mantle composition,mantle evolution,PGE fractionation and mineralization.Geochim Cosmochim Acta75:1621-1641
    Zhou MF,Robinson PT,Lesher CM,Keays RR,Zhang CJ,Malpas J(2005)Geochemistry,petrogenesis and metallogenesis of the Panzhihua gabbroic layered intrusion and associated Fe-Ti-Voxide deposits,Sichuan Province,SW China.J Petrol46:2253-2280
    Zhou MF,Ma YX,Yan DP,Xia XP,Zhao JH,Sun M(2006)The Yanbian terrane(southern Sichuan Province,SW China):a Neoproterozoic arc assemblage in the western margin of the Yangtze Block.Precambrian Res 144:19-38
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