摘要
研究了一种脂肪酸碳纳米管蓄能复合材料,能更广泛地应用于各类蓄能空调系统中。基于脂肪酸复合材料制备的理论基础,计算得出理论配合比,再经过反复实验得出最佳配合比,最后添加少量的碳纳米管以增强其导热性,在碳纳米管用量为0.8%(wt,质量分数)条件下,制得的脂肪酸碳纳米管蓄能材料的固态导热系数为0.293W/(m·℃),液态导热系数为0.581W/(m·℃),分别比脂肪酸共晶体系提高33%和35%。
A kind of energy storage material mixed by fatty acid &carbon nanotubes was researched,which can apply to many kinds of energy storage air-conditioning system.The match scale of theory was figured out based on the theory of preparation of composite material.The optimum match scale was got after repeated experiment and added a little quantity of carbon nanotubes to enhance the thermal conductivity.When the mass fraction of carbon nanotubes was0.8 wt%,the material had the solid thermal conductivity of 0.293 W/(m·℃)and the liquid thermal conductivity of0.581 W/(m·℃),respectively 33% and 35% higher than the fatty acid eutectic system.
引文
[1]李明财,郭军,史珺,等.利用采暖/制冷度日分析建筑能耗变化的适用性评估[J].气候变化研究进展,2013,9(1):43-48.
[2]伍小亭.暖通空调系统节能设计思考[J].暖通空调,2012,42(7):1-11.
[3]刘程,袁艳平,张楠,等.脂肪酸三元低共熔混合物相变温度和潜热的理论预测[J].材料导报,2014,28(1):165-168.
[4]李钰.石蜡基复合相变材料的研究及在热泵系统中的应用[D].南昌:南昌大学,2015.
[5]黄民富,魏嘉麒,曾效舒,等.球磨分散工艺对碳纳米管分散的影响[J].材料导报,2013,27(22):35-38.
[6]朱天舒,李明.纳米材料体等离子能的尺寸与维度效应[J].吉林师范大学学报(自然科学版),2015,36(2):32-35.
[7]李敏,王绍凯,顾轶卓,等.碳纳米管有序增强体及其复合材料研究进展[J].航空学报,2014,35(10):2699-2721.
[8]李艳.相变储能材料热性能研究[D].济南:山东轻工业学院,2012.
[9]Nurettin Sahiner,Selin Sagbas,Nahit Aktas.Preparation of macro-,micro-and nano-sized poly(tannic acid)particles with controllable degradability and multiple biomedical uses[J].Polymer Degradation and Stability,2016,129(10):96-105.
[10]郑文娟.石蜡/铜纳米粒子复合相变材料储热性能的研究[D].青岛:青岛科技大学,2012.