Rapid visualization of latent fingerprints using novel CaSiO_3:Sm~(3+) nanophosphors fabricated via ultrasound route

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英文篇名：Rapid visualization of latent fingerprints using novel CaSiO_3:Sm~(3+) nanophosphors fabricated via ultrasound route 作者：R.B.Basavaraj ; G.P.Darshan ; B.Daruka ; Prasad ; S.C.Sharma ; H.Nagabhushana 英文作者：R.B.Basavaraj;G.P.Darshan;B.Daruka Prasad;S.C.Sharma;H.Nagabhushana;Prof.C.N.R.Rao Centre for Advanced Materials, Tumkur University;Department of Physics, Acharya Institute of Graduate Studies;Department of Physics, B M S Institute of Technology and Management,VTU Affiliated;Department of Mechanical Engineering, Jain University,Advisor, Jain Group of Institutions; 英文关键词：Ultrasonication synthesis;;Photoluminescence;;Fingerprint;;Photometric properties;;Judd-Ofelt analysis;;Rare earths 中文刊名：YXTB 英文刊名：稀土学报(英文版) 机构：Prof.C.N.R.Rao Centre for Advanced Materials, Tumkur University;Department of Physics, Acharya Institute of Graduate Studies;Department of Physics, B M S Institute of Technology and Management,VTU Affiliated;Department of Mechanical Engineering, Jain University,Advisor, Jain Group of Institutions; 出版日期：2019-01-15 出版单位：Journal of Rare Earths 年：2019 期：v.37 基金：DST-SERB (Project No.SR/FTP/PS-135/2010), New Delhi, India for the funding of this project 语种：英文; 页：YXTB201901005 页数：13 CN：01 ISSN：11-2788/TF 分类号：38-50

摘要

Latent fingerprints (LFPs) were the most significant identification method for individualization. Most commonly available fingerprints (FPs) in crime spot investigation were latent and patent types. Generally,LFPs were invisible and thus the effective visualization technique necessitates for the analysis of such FPs. In the past years, many traditional visualization techniques have been employed, but suffered with low resolution, sensitivity, contrast and high background noise. To overcome such limitations, we synthesized Sm~(3+) doped CaSiO_3 nanophosphors (NPs) via an ultrasound irradiation route using mimosa pudica (m. p.)leaves extract as a bio-surfactant. The morphological behavior of the prepared samples was extensively studied by varying the concentration of the m. p. extract, ultrasound irradiation duration, pH level of the precursor solution and sonication power. The photoluminescence (PL) emission spectra exhibit characteristic peaks at～561,601 and 647 nm, which were attributed to~5G_(5/2)→~6H_J(J=5/2,7/2 and 9/2) transitions of Sm~(3+) ions.The Judd-Ofelt(J-O) intensity parameters and other radiative properties were estimated using PL data. The Commission International de I'Eclairage (CIE) color coordinates were positioned in orange-red region shows average correlated color temperature (CCT) value of～3576 K. The optimized samples can be used as a labeling agent for the visualization of LFPs on various porous and non-porous surfaces under normal light irradiation. The visualized FPs reveals well defined ridge characteristics, namely whorl, loop,arch, bifurcation, eye, island, bridge, sweat pores, etc, with high sensitivity, selectivity, low contrast and background hindrance. Aforementioned results evidence that the prepared CaSiO_3:Sm~(3+) NPs were promising luminescent materials for solid state lighting and forensic applications.
        Latent fingerprints(LFPs) were the most significant identification method for individualization. Most commonly available fingerprints(FPs) in crime spot investigation were latent and patent types. Generally,LFPs were invisible and thus the effective visualization technique necessitates for the analysis of such FPs. In the past years, many traditional visualization techniques have been employed, but suffered with low resolution, sensitivity, contrast and high background noise. To overcome such limitations, we synthesized Sm~(3+) doped CaSiO_3 nanophosphors(NPs) via an ultrasound irradiation route using mimosa pudica(m. p.)leaves extract as a bio-surfactant. The morphological behavior of the prepared samples was extensively studied by varying the concentration of the m. p. extract, ultrasound irradiation duration, pH level of the precursor solution and sonication power. The photoluminescence(PL) emission spectra exhibit characteristic peaks at～561,601 and 647 nm, which were attributed to ~5 G_(5/2)→~6 H_J(J= 5/2,7/2 and 9/2) transitions of Sm~(3+) ions.The Judd-Ofelt(J-O) intensity parameters and other radiative properties were estimated using PL data. The Commission International de I'Eelairage(CIE) color coordinates were positioned in orange-red region shows average correlated color temperature(CCT) value of ～3576 K. The optimized samples can be used as a labeling agent for the visualization of LFPs on various porous and non-porous surfaces under normal light irradiation. The visualized FPs reveals well defined ridge characteristics, namely whorl, loop,arch, bifurcation, eye, island, bridge, sweat pores, etc. with high sensitivity, selectivity, low contrast and background hindrance. Aforementioned results evidence that the prepared CaSiO_3:Sm~(3+) NPs were promising luminescent materials for solid state lighting and forensic applications.

引文

1. Wang M, Li M, Yang MY, Zhang XM, Yu AY, Zhu Y, et al. NIR-induced highly sensitive detection of latent fingermarks by NaYF4:Yb,Er upconversion nanoparticles in a dry powder state. Nano Res. 2015;8:1800.
    2. Basavaraj RB, Nagabhushana H, Darshan GP, Daruka Prasad B, Rahul M,Sharma SC, et al. Red and green emitting CTAB assisted CdSiO_3:Tb~(3+)/Eu~(3+)nanopowders as fluorescent labeling agents used in forensic and display applications. Dyes Pigments. 2017;147:364.
    3.Darshan GP, Premkumar HB, Nagabhushana H, Sharma SC, Daruka Prasad B,Prashantha SC, et al. Superstructures of doped yttrium aluminates for luminescent and advanced forensic investigations. J Alloys Compd. 2016;686:577.
    4. Basavaraj RB, Nagabhushana H, Darshan GP, Daruka Prasad B, Sharma SC,Venkatachalaiah KN. Ultrasound assisted rare earth doped Wollastonite nanopowders:labeling agent for imaging eccrine latent fingerprints and cheiloscopy applications.J Ind Eng Chem. 2017;51:90.
    5. Sharma V, Das A, Kumar V, Ntwaeaborwa OM, Swart HC. Potential of Sr_4Al_(14)O_(25):Eu~(2+),Dy~(3+)inorganic oxide-based nanophosphor in latent fingermark detection. J Mater Sci. 2014;49:2225.
    6. Chen H, Ma RL, Chen Y, Fan LJ. Fluorescence development of latent fingerprint with conjugated polymer nanoparticles in aqueous colloidal solution. ACS Appl Mater Interfaces. 2017;9:4908.
    7. Park SJ, Kim JY, Yim JH, Kim NY, Lee CH, Yang SJ, et al. The effective fingerprint detection application using Gd_2Ti_2O_7:Eu~(3+)nanophosphors.J Alloys Compd.2018;741:246.
    8. Rohini BS, Nagabhushana H, Darshan GP, Basavaraj RB, Sharma SC, Amudha P,et al. Multifunctional applications of self-assembled 3D CeO_2:Cr~(3+)hierarchical structures synthesized via ultrasound assisted sonochemical route. J Alloys Compd. 2017;724:897.
    9. Park JY, Yang HK. Novel red-emitting Y_4Zr_3O_(12):Eu~(3+)nanophosphor for latent fingerprint technology. Dyes Pigments. 2017;141:348.
    10. Raju GSR, Park JY,Nagaraju GP, Pavitra E, Yang HK, Moon BK, et al. Evolution of CaGd_2ZnO_5:Eu~(3+)nanostructures for rapid visualization of latent fingerprints.J Mater Chem C. 2017;5:4246.
    11. Venkataravanappa M, Basavaraj RB, Darshan GP, DarukaPrasad B, Sharma SC,Hema Prabha P, et al. Multifunctional Dy(Ⅲ)doped di-calcium silicate array for boosting display and forensic applications.J Rare Earths. 2018;36:690.
    12. Singh S, Srivastava VC, Lo SL, Mandal TK, Naresh G. Morphology-controlled green approach for synthesizing the hierarchical self-assembled 3D porous ZnO superstructure with excellent catalytic activity. Microporous Mesoporous Mater. 2017;239:296.
    13. Beepthi NH, Darshan GP, Basavaraj RB, Daruka Prasad B, Nagabhushana H.Large-scale controlled bio-inspired fabrication of 3D CeO_2:Eu~(3+)hierarchical structures for evaluation of highly sensitive visualization of latent fingerprints.Sens Actuators B. 2018;255:3127.
    14. Venkataravanappa M, Nagabhushana H, Darshan GP, Sharma SC, Archana KV,Basavaraj RB, et al. Facile ultrasound route for the fabrication of green emitting Ba_2SiO_4;Eu~(2+)nanophosphors for display and dosimetric applications. Mater Res Bull. 2018;97:281.
    15. Suslick KS. Rev. Applications of ultrasound to materials chemistry. Mater Sci.1999;29:295.
    16. Basavaraj RB, Nagabhushana H, Daruka Prasad B, Vijayakumar GR. Zinc silicates with tunable morphology by surfactant assisted sonochemical route suitable for NUV excitable white light emitting diodes. Ultrason Sonochem.2017;34:700.
    17. Venkatachalaiah KN, Nagabhushana H, Darshan GP, Basavaraj RB, Daruka Prasad B, Sharma SC. Blue light emitting Y_2O_3:Tm~(3+)nanophosphors with tunable morphology obtained by bio-surfactant assisted sonochemical route.Spectrochim Acta Part A. 2017:184:89.
    18. Dhanalakshmi M, Nagabhushana H, Darshan GP, Basavaraj RB, Daruka Prasad B.Sonochemically assisted hollow/solid BaTiO_3:Dy~(3+)microspheres and their applications in effective detection of latent fingerprints and lip prints. J Sci Adv Mater Devices. 2017;2:22.
    19. Venkataravanappa M, Nagabhushana H, Daruka Prasad B, Darshan GP,Basavaraj RB, Vijayakumar GR. Dual color emitting Eu doped strontium orthosilicate phosphors synthesized by bio-template assisted ultrasound for solid state lightning and display applications. Ultrason Sonochem. 2017;34:803.
    20. Huang JS, Liu RH, Liu YH, Hu YS, Chen GT, Yan CP, et al. Effect of fluxes on synthesis and luminescence properties of BaSi_2O_2N_2:Eu~(2+)oxynitride phosphors. J Rare Earths. 2018;36:225.
    21. Linganna K, Narro-Garcia R, Manasa P, Desirena H, Rosa E De la, Jayasankar CK.Effect of BaF_2 addition on luminescence properties of Er~(3+)/Yb~(3+)co-doped phosphate glasses. J Rare Earths. 2018;36:58.
    22. Wan Y, Abudouwufu T, Yusufu T, He JY, Sidike A. Photoluminescence properties and energy transfer of a single-phased white-emitting NaAlSiO_4:Ce~(3+),Sm~(3+)phosphor.J Rare Earths. 2017;35:850.
    23. Man XQ, Yu LX, Sun JJ, Li SC, Zhong JL Synthesis and photoluminescent properties of Eu~(3+)/Dy~(3+)doped SrO-Al_2O_3-SiO_2 glass-ceramics. J Rare Earths.2017;35:446.
    24. Sunitha DV, Nagabhushana H, Singh Fouran, Dhananjaya N, Sharma SC,Nagabhushana BM, et al. Swift heavy ion induced structural, iono and photoluminescence properties ofβ-CaSiO_3:Dy~(3+)nanophosphor. Spectrochim Acta Part A. 2012;93:300.
    25. Wan XH, Hu AM, Li M, Chang CK, Mao DL. Performances of CaSiO_3 ceramic sintered by Spark plasma sintering. Mater Charact. 2008;59:256.
    26. Wang VVZ, Zhang SY, Wang LJ, Shi HL. A facile and environmentally friendly NaCl nonaqueous ionic liquid route to prepare crystallineβ-CaSiO_3 nanowires.Mater Sci Eng C. 2013;33:2288.
    27. Wu J, Zhu YJ, Cheng GF, Huang YH. Microwave-assisted preparation of Ca_6Si_6O_(17)(OH)_2 andβ-CaSiO_3 nanobelts. Mater Res Bull. 2010;45:509-
    28. Wu CT, Ramaswamy Y, Kwik D, Zreiqat H. The effect of strontium incorporation into CaSiO_3 ceramics on their physical and biological properties. Biomaterials.2007;28:3171.
    29. Madesh Kumar M, Nagabhushana H, Nagabhushana BM, Suriyamurthy N,Sharma SC, Shivakumara C, et al. Synthesis, characterization and spectroscopic investigation of Cr~(3+)doped wollastonite nanophosphor. Spectrochim Acta, Part A. 2014;128:403.
    30. Nagabhushana H, Nagabhushana BM, Madesh Kumar M, Chikkahanumantharayappa, Murthy KVR, Shivakumara C, et al. Synthesis, characterization and photoluminescence properties of CaSiO_3:Eu~(3+)red phosphor. Spectrochim Acta Part A. 2011;78:64.
    31. Zhou L,Yan B. Sol-gel synthesis and photoluminescence of CaSiO_3:Eu~(3+)nanophosphors using novel silicate sources. J Phys Chem Solid. 2008;69:2877.
    32. Fu LL,Yang XX, Fu ZL, Wu ZJ, Jeong JH. Hydrothermal synthesis and tunable luminescence of CaSiO_3:RE~(3+)(RE~(3+)=Eu~(3+), Sm~(3+),Tb~(3+), Dy~(3+))nanocrystals.Mater Res Bull. 2015;65:315.
    33. Wang W, Lei X, Ye ZT, Zhao N, Yang H. The luminescent properties and latent fingerprint identification application of AlN:Ce,Tb phosphors.J Alloys Compd.2017;705:253.
    34. Fernandes D, Krysmann MJ, Kelarakis A. Carbon dots based nanopowders and their application for fingerprint recovery, Chem Commun.2015;51:4902.
    35. Fernandes D, Krysmann MJ, Kelarakis A. Carbogenically coated silica nanoparticles and their forensic applications. Chem Commun. 2016;52:8294.
    36. Yu YL, Yan L, Xia ZN. Non-toxic luminescent Au Nanoclusters@Montmorillonite nanocomposites powders for latent fingerprint development. RSCAdv. 2017;7:50106.
    37. Malik AH, Kalita A, Iyer PK. Development of well preserved, substrate-versatile latent fingerprints by aggregation induced enhanced emission active conjugated polyelectrolyte. ACS Appl Mater Interfaces. 2017;9:37501.
    38. Jiang BP, Yu YX, Guo XL, Ding ZY, Zhou B, Liang H, et al. White-emitting carbon dots with long alkyl-chain structure:effective inhibition of aggregation caused quenching effect for label-free imaging of latent fingerprint. Carbon. 2018; 128:12.
    39. Venkataravanappa M, Nagabhushana H, Darshan GP, Daruka Prasad B,Vijayakumar GR, Premkumar HB, et al. Novel EGCG assisted ultrasound synthesis of self-assembled Ca_2SiO_4:Eu~(3+)hierarchical superstructures:photometric characteristics and LED applications. Ultrason Sonochem.2016;33:226.
    40. Mickens MA, Assefa Z. Tunable luminescence and white light emission of novel multiphase sodium calcium silicate nanophosphors doped with Ce~(3+), Tb~(3+), and Mn~(2+)ions.J Lumin. 2014;145:498.
    41. Sandhyarani A, Kokila MK, Darshan GP, Basavaraj RB, Daruka Prasad B,Sharma SC, et al. Versatile core-shell SiO_2@SrTiO_3:Eu~(3+),Li~+nanopowders as fluorescent label for the visualization of latent fingerprints and anticounterfeiting applications. Chem Eng J.2017;327:1135.
    42. Dhoble SJ, Dhoble NS, Pode RB. Preparation and characterization of Eu~(3+)activated CaSiO_3,(CaA)SiO3[A=Ba or Sr] phosphors. Bull Mater Sci. 2003;26:377.
    43. Manohar T, Prashantha SC, Ramachandra Naik, Nagabhushana H,Nagaswarupa HP, Anantharaju KS, et al. A benign approach for tailoring the photometric properties and Judd-Ofelt analysis of LaAlO_3:Sm~(3+)nanophosphors for thermal sensor and WLED applications. Sens Actuators, B. 2017;243:1057.
    44. Suresh C, Nagabhushana H, Basavaraj RB, Darshan GP, Kavyashree D, Daruka Prasad B, et al. SiO_2@LaOF:Eu~(3+)core-shell functional nanomaterials for sensitive visualization of latent fingerprints and WLED applications. J Colloid Interface Sci. 2018;518:200.
    45. Gopi D, Shinyjoy E, Karthika A, Nithiya S, Kavitha L, Rajeswari D, et al. Single walled carbon nanotubes reinforced mineralized hydroxyapatite composite coatings on titanium for improved biocompatible implant applications. RSC Adv. 2015;5:36766.
    46. Kang XJ, Huang SS, Yang PP, Ma PA, Yang DM, Lin J. Preparation of luminescent and mesoporous Eu~(3+)/Tb~(3+)doped calcium silicate microspheres as drug carriers via a template route, Dalton Trans, 2011;40:1873.
    47. Ebbert C, Grundmeier G, Buitkamp N, Kroger A, Messerschmidt F, Thissen P.Toward a microscopic understanding of the calcium-silicate-hydrates/water interface. Appl Surf Sci. 2014;290:207.
    48. Wang GQ, Gong XH, Lin YF, Chen YJ, Huang JH, Luo ZD, et al. Polarized spectral properties of Sm~(3+):LiLuF_4 crystal for visible laser application. Opt Mater.2014;37:229.
    49. Jorgensen CK, Reisfeld R. Judd-Ofelt parameters and chemical bonding. J Less Comm Metal. 1983;93:107.
    50. Jing F, Zhang HJ. Hybrid materials based on lanthanide organic complexes:a review. Chem Soc Rev. 2013;42:387.
    51. Kodaira CA, Brito HF, Malta OL, Serra OA. Luminescence and energy transfer of the europium(Ⅲ)tungstate obtained via the Pechini method. J Lumin.2003;101:11.
    52. Publication CIE no 17.4. International lighting vocabulary. Vienna, Austria:Central Bureau of the Commission Internationale de L'Eclairage; 1987.
    53. McCamy CS. Correlated color temperature as an explicit function of chromaticity coordinates. Color Res Appl. 1992;17:142.
    54. Basavaraj RB, Nagabhushana H, Daruka Prasad B, Sharma SC, Venkatachalaiah KN.Mimosa pudica mediated praseodymium substituted calcium silicate nanostructures for white LED application J Alloys Compd. 2017;690:730.