驻极体滤料对微细颗粒物分级效率的试验研究
详细信息    本馆镜像全文|  推荐本文 |  |   获取CNKI官网全文
摘要
随着科技的进步与工业技术的发展,人民群众的生活水平在逐渐的提高,人们对自身健康的关注程度也相应提高,但随之带来的大气污染问题也日益严重,这便造成了人民群众对自身健康的逐渐重视与大气空气质量污染问题的持续出现之间的矛盾。
     目前在我国的大气污染物中,可吸入颗粒物已经成为最主要的污染成分而对人们的身体健康造成了极大的危害。作为条件更为苛刻的室内空气环境来说,其中的可吸入颗粒物质量浓度较室外更高,人员停留的时间也更久,因此室内可吸入颗粒物质量浓度的高低对人体造成的危害远比室外更大,也更应受到重视。正因如此,空气过滤技术作为民用舒适性室内空间中降低可吸入颗粒物质量浓度最有效、最经济的方法之一而受到了各界的关注,对其相关研究也逐渐展开。其中过滤材料作为过滤系统的核心原件,其性能的高低直接影响到过滤系统的使用效果,因此对其的研究一直是重中之重。
     目前民用舒适性空间内的可吸入颗粒物浓度均以PM_(10)的浓度值作为衡量指标,这个设计指标在我国于2003年颁布并开始强制实施。而随着对可吸入颗粒物研究的深入,粒径的细分化已经成为目前的主流趋势并逐渐应用于实践当中。例如,在美国,便已于今年开始分地区分时段的应用更为严格的PM_(2.5)标准,由此可以看出,随着PM_(10)标准在我国的普及以及PM_(2.5)标准在欧美国家的逐渐发展,后者在我国的推广与相关标准的制定也是势在必行的。
     目前我国对于民用舒适性空间内的可吸入颗粒物通常使用粗效滤料进行过滤,少量使用中效滤料,而通过大量实验研究及应用可以发现粗、中效滤料对PM_(10)的过滤效果甚微,而对PM_(2.5)则基本无效;高效滤料虽然效果较好,但因其过滤阻力太大,造成系统能耗增加,导致成本升高,因此也无法应用于民用室内空间的空气过滤,所以,挑选一种新型过滤材料来满足舒适性空间内的PM_(10)标准乃至即将到来的PM_(2.5)标准,保护人们群众的身体健康便成为一项刻不容缓的工作。
     驻极体滤料作为一种“高效低阻”的新型的过滤材料目前正逐渐受到重视,但是对其过滤特性的相关实验研究仍然较少,因此对其是否适用于民用空气过滤技术中尚无定论,本课题则通过对不同的过滤风速、克重、阻力压降、容尘量、过滤对象粒径大小等条件下驻极体过滤材料的过滤性能进行了详细的实验研究及分析讨论。同时,为了能更有针对性的对不同粒径大小的颗粒物的过滤效率进行分析,以便更有针对性的对滤料材料进行性能检测,在实验之前,笔者对多处室内环境进行了实地调研,具体包括多处不同功用的公共建筑及多处不同条件下的办公室环境,通过调研对不同类型的室内环境中颗粒物浓度的分布特性及颗粒物质量(数量)浓度的影响因素等进行了详细分析,并得出了较为有意义的结论,为课题的进行打下了良好的理论基础。
     而为了能早日的将驻极体过滤材料应用到工程实践中去,本论文又以之前所调研监测的某办公室为原型,建立了不同空气过滤方式下室内颗粒物质量浓度的稳态模型,并通过计算推导得出了室内颗粒物瞬时浓度、稳定浓度、过滤时间等表达式,然后将粗中高效滤料及多种驻极体滤料的实际实验检测数值代入后进行求解分析,通过分析后发现,驻极体滤料的过滤性能较粗中高效过滤材料更为优良。同时也对不同空气过滤方式下室内颗粒物稳定浓度大小,达到稳定所需时间等进行了理论分析,以期能为工程实际应用中驻极体滤料的早日应用及空气过滤方式的选择提供一定的理论依据。不仅如此,本课题在进行颗粒物谱分布变化曲线及滤料分级效率的原始数据处理上采用了数学方程式拟合的方法来进行表示,通过原始数据与拟合曲线的对比可以更为清楚的看出其各项变化的趋势,以方便对其进行规律性总结,并通过所得拟合方程式来对颗粒物浓度、滤料分级效率等进行估算或验算。
     本课题的研究以驻极体滤料的过滤性能及相关因素研究为主,并得出一定结论;同时也通过前期调研监测,对多种公用及办公建筑的室内环境中可吸入颗粒物的实际分布状况及颗粒物浓度影响因素进行了归纳总结,并对这些研究采用了数学拟合的方式进行规律性总结,通过这些研究不仅能对室内可吸入颗粒物的分布特性有了更加深入的了解,更能为驻极体过滤材料的早日应用提供有益的指导建议,从而达到保护人民群众身体健康的最终目标!
With the improvement of science and technology, people's standard of living has improved gradually and people are paying more and more attention to the health of themselves, but the airborne contamination is becoming worse too, all of these lead to a contradiction between the people's recognition on theire health and the deterioration of the air quality.
     Now the IP(Inhalable Particles) has become the uppermost contamination in the atmosphere in our country and do more harm to our health. More rigorous condition were required for the indoor air environment where the concentration of IP is high and people stay more time in, so we should pay more attention to the indoor IP concentration than that of out door. As one of the most effective and economical methods which can reduce the concentration of IP , the way of air filtration has gained more attention from all circles and some research has began gradually. The Filtration material is the hard core of the whole system, its performance influence the effect of filtration system directly, so the research on it is the most important.
     Normally, we use the PM_(10) which was executed in 2003 as the index of IP's concentration in the comfortable indoor environment. But with the deep development of research , we found a derection that the object has changed to the more tiny than now. Such as in USA, the standard of PM_(2.5) which is more strict than PM_(10) has applied according to the different area and the different period of time from this year. So we can say that with the popularity of the standard PM10 in our country and the development of standard PM2.5 in Europe and American , the establishment and spread of the later standard will carry out sooner or later.
     Now we usually use the low-efficiency in the air filtration system and sometime use the middle-efficiency, but both of this played a unimportant part to the PM10 and nearly useless to the PM_(2.5), although the high-efficiency filtration material is good ,but the higher resistance will cost more energy, so it seldom be used in the comfortable air filtration system. From all of this we found it's urgent to pick up a kind of new filtration material to purifying the IP and to protect our health.
     The Electret filtration material has been recognized by more and more people for it's great performance, but there is still no conclusion that if it's useful for the comfortable air environment, because the experiments about the performance are few. In this paper ,we have done a great deal of experiments to test the efficiency of electret filtration material to the IP. In order to get a more exact result, at first, we picked up some public buildings and office to monitor and then we analyzed those data to educe a significative conclision which can be the foundation of this research
     For applying the electret filtration material to project as soon as posible, in this paper, according to the information surveyed, we build a model of IP's concentration under different melthod of air-filtration, then obtain some formulas such as the instantaneous concentration, steady concentration, time of filtration and so on, take the result which had obtained before to those formulas and analyzed. From those, we found that electret filtration material is better than the low or middle filtration material, and I hope all of these conclusion will be helpful to the application of electret filtration material so as to gain the final aim of protecting people's health.
引文
[1]国家环境保护总局,《2005年中国环境状况公报》,http://www.zhb.gov.cn/;
    [2]上海市环境保护宣传中心,《2005年上海市环境质量公报》,2006.6,http://www.sepb.gov.cn/;
    [3]沈晋明,上海办公大楼空气品质客观评价,通风除尘,1995,14(4),14~17;
    [4]蒋红梅,大气可吸入颗粒物的研究进展,环境科学动态,2001年第一期,11~15;
    [5]原福胜,马亚萍,赵五红.不同粒径颗粒物对人双核淋巴细胞微核率的影响[J].卫生毒理学杂志,1999,13(2):231~237;
    [6]GB 3095-82,《大气环境质量标准》,国务院环境保护领导小组,1982;
    [7]GB 11667-89,《居住区大气中可吸入颗粒物卫生标准》,中华人民共和国卫生部卫生监督司,1989;
    [8]GB3095-1996,《环境空气质量标准》,国家环境保护局,1996;
    [9]GB/T 17095-1997,《室内空气中可吸入颗粒物卫生标准》,中华人民共和国卫生部,1997;
    [10]GB/T 18883-2002,《室内环境质量标准》,国家环境保护总局,2002
    [11]美国环保署,http://www.eqa.gov/;
    [12]Kleeman M J, Cass G R. Source contributions to the size and composition distribution of urban particulate air pollution[J], Atmospheric Environment, 1998. 132(16): 2803—2816
    [13]Ramsden A R. Shiraoka M. Transfer of a single particle for combined ESEM and TEM analyses [J]. Atmospheric Environment, 1982, 16{21) 949—961.
    [14]Beguma B A, Kimb E, Biswas S K, etal. Investigation of sources of atomspheric at urban and semi-urban areas in Bangladesh[J]. Atmospberi(Environment, 2004, 38(8): 3025—3038
    [15]王华英,过滤材料对PM10的过滤性能研究,[学位论文],东华大学图书馆,2004
    [16]虞霞,民用空调系统中控制颗粒物浓度用纤维过滤器的测试及应用研究,[学位论文],东华大学图书馆,2005
    [17]朱晖,环境空气中微粒过滤材料性能的实验研究,[学位论文],东华大学图书馆,2005
    [18]谭亮亮,建筑环境空气过滤微细颗粒物技术的试验研究,[学位论文],东华大学图书馆,2006
    [19]Y.C. Ahn, S.K. Park, G.T. Kim, Development of high efficiency nanofilters made of nanofibers, Current Applied Physics, Volume 6, Issue 6, October 2006, 1030-1035
    [20]岳伟生,李晓林,李燕,用质子微探针研究上海吴淞空气含铅颗粒物来源,中国环境科学,2003.23.6
    [21]郝明途,城市大气颗粒物来源解析研究,[学位论文],山东大学,2005
    [22]Wayne R. Ott, Hans C. Siegmann, Using multiple continuous fine particle monitors to characterize tobacco, incense, candle, cooking, wood burning, and vehicular sources in indoor, outdoor, and in-transit settings, Atmospheric Environment, Volume 40, Issue 5, February 2006, 821-843
    [23]A. Hemes, a, J. H. M. Wostenb, A. Lillyc and J. H. Oude Voshaar, Evaluation of different procedures to interpolate particle-size distributions to achieve compatibility within soil databases,, Volume 90, Issues 3-4, July 1999, 187-202
    [24]易帆,城市大气中可吸入颗粒物的来源分析,[学位论文],华中科技大学,2004
    [25]田伟 陈刚才 陈克军,室内空气中颗粒物对人体健康的影响,重庆环境科学,2002.10,58~61
    [26]Wieslaw A. Jedrychowskia, Frederica P. Pererab, Agnieszka Pac, Variability of total exposure to PM2.5 related to indoor, and outdoor pollution sources Krakow study in pregnant women,, Volume 366, Issue 1,31 July 2006, Pages 47-54
    [27]H. Wise,D. Balharry, L.J. Reynolds, K. Sexton and R.J. Richards, Conventional and toxicogenomic assessment of the acute pulmonary damage induced by the instillation of Cardiff PM10 into the rat lung, Science of The Total Environment Volume 360, Issues 1-3,1 May 2006, 60-67
    [28]胡伟 魏复盛 滕恩江,空气污染对儿童及其父母呼吸系统健康的影响,中国环境科学,2000年05期,425~428
    [29]Ostro B D, Lipsett M J, Mann J K, et al. Air pollution and asthma exacerbations among African-American children in Los Angeles [J]. Inhalation Toxicol, 1995,7:711-722.
    [30]Ethel Brits, Greet Schoeters, Luc Verscbaeve, Genotoxicity of PM10 and extracted organics collected in an industrial, urban and rural area in Flanders, Belgium, Environmental Research, Volume 96, Issue 2, October 2004, 109-118
    [31]董雪玲,大气可吸入颗粒物对环境和人体健康的危害,资源·产业,2004,6.5,50~53
    [32]S.R.C. Soares, H. M. Bueno-Guimaraes, C. M. Ferreira, Urban air pollution induces micronuclei in peripheral erythrocytes of mice in vivo, Environmental Research, Volume 92, Issue 3, July 2003, 191-196
    [33]贾健,徐伟,阚海东,上海市闸北区大气PM10对居民健康影响的定量评价,环境与职业医学,2005.22.5,399~402
    [34]戴海夏,宋伟民,高翔,上海市A城区大气PM10、PM2.5污染与居民日死亡数的相关分析,卫生研究,2004.33.3,293~297
    [35]Schwartz.JPM2.5对人体的危害
    [36]黄齐模等,纺织品过滤材料,北京,纺织工业出版社,1992,5~20
    [37]蔡杰著,窄气过滤ABC,北京,中国建筑工业出版社2002,40~62
    [38]姜坪 刘梅红,空气过滤材料的发展与应用,现代纺织技术,52~55
    [39]王继祖等,非织造布产品的应用及设计,中国纺织出版社1996,109~133
    [40]马建伟,郭秉臣,陈韶娟主编,非织造布技术概论,中国纺织出版社2004,12~51
    [41]Peter P.Tsai崔爱锋,世界非织造过滤材料的现状和未来,产业用纺织品,编辑部邮箱2001年03期,1~3
    [42]Ahlstrom's Francesca Montefuseo, The use of Nonwovens in air filtration, Filtration & Separation, Volume 42, Issue 2, March 2005, Pages 30-3;
    [43]谢小军,黄翔,狄育慧,驻极体空气滤材质量的主要评价指标初探,纺织科技进展,2005.5,32~36
    [44]程灯塔,刘刚,陆斌,新型驻极体过滤材料在分体空调机上的应用,洁净与空调技术,2005.1,26~30
    [45]康卫民,程博闻,焦晓宁等,驻极体非织造布的研究进展,产业用纺织品,2005.23.2,1~5
    [46]I. Krucinska, The influence of technological parameters on the filtration efficiency of electret needled non-woven fabrics, Journal of Electrostatics Volume 56, Issue 2,26 September 2002, 143-153
    [47]Lee.K.W.and Liu,B.Y.H,Aerosol Science Technology, 1982,1,35
    [48]Dorman, R. G., In High Efficiency Air Filtration,Buterworth, London, 1964
    [49]Davies, C. N., Definitive equations for the fluid resistance of spheres. Proc. Phys.Soc. 1945, 57, 259~270
    [50]Dawson, S. V, Theory of collection of airborne particles bu fibrous filters, Se. D.Thesis, Harvard School of Public Health, 1969
    [51]Ronard G.Stafford and Harry J.Ettinger. Comparison of Filter Media Against Liquid and Solid Aerosols. American industial hygiene association Journal, V32,No.5,309~326,1971
    [52]Shapiro,M., An analytical model for aerosol filtration by nonuniform filter media, J. Aerosol Sci., 1966,27,263~280
    [53]Friedlander, S. K., Theory of aerosol filtration, Ind, Eng. Chem., 1958, 50,1161~1164
    [54]Chen,C,Y, Filtration of Aerosols by Fibrous Filters,Chem,Rev,1955,55,595;
    [55]Liu, B. Y H., and Rubow, K. L., Process of the 5's World Filtration ongress,Nice, Paris, 1990, 3, 112
    [56]Pich, J, Pressure drop of fibrous filters at small Knudsen numbers,Ann.Occup.Hyg, 1996,9,23~27;
    [57]Chert, C. Y, Filtration of Aerosols by Fibrous Filters, Chem. Rev., 1955, 55, 595
    [58]王旭,焦晓宁,赵小翠等,针刺非织造布的空气净化过滤材料的实验与分析,洁净与空调技术,2006.1,16~18
    [59]蔡杰,空气过滤器专题讲座空气过滤原理(讲座一),洁净与空调技术,2002.3,60~63;
    [60]蔡杰,空气过滤器应用问题,第五届中国国际(北京)洁净技术论坛,2002.11.27,443~461
    [61]C.N戴维斯著,黄日广译,空气过滤,北京原子能出版社,1979:6
    [62]张国权,气溶胶力学—除尘净化理论基础,北京中国环境科学出版社,1987
    [63]Clyde Orr, Filtration Principles and Practices, Marcel Dekker, Inc, New York, 1977
    [64]I.B. Stechkina and N. A. Fuchs, Studies on fibrous aerosol filters, Ⅳ Calculation of aerosol deposition in model filters in the range of maximum penetration, Ann.Occup. Hyg. 1969,12,1~8
    [65]张久政,高院安,黄惠文等,理想纤维过滤材料的影响因素,过滤与分离,2006.16.2 39~41;
    [66]聂雪丽,石珉,陈玉华等,高效空气过滤器检测结果的探讨,轻工机械,2006/24/2,168~170;
    [67]付海明,张鹏峰,亢燕铭等,空气过滤捕集效率影响因素分析及多元关联式的确定,2006.2,25~28
    [68]喻晓玲,靳向煜,YU Xiao-ling等,设计纤维制品过滤材料的影响因素,过滤与分离,2005.15.3,36~38
    [69]Davis,C.N,Air Filtration, Academie,Press,London,1973;
    [70]陈宇炼,吴冬梅,钱婕等,吸烟者呼出气中一氧化碳、可吸入颗粒物测定,中国公共卫生,2004.20.3,333
    [71]谭亮亮,邹钺,沈恒根,各种过滤器试验方法和分类之比较,过滤与分离,2005.15.4,43~47
    [72]许钟麟,空气洁净技术原理(第2版),上海,同济大学出版社,1998
    [73]《空气调节设计手册》,中国建筑年工业出版社,1983,
    [74]徐文华,舒适性空调空气过滤器效率计算方法,暖通空调,2001年第31卷第3期,42~44
    [75]白玮、韩华、龙惟定等,空调系统新风供给形式对室内颗粒物污染物的影响,建筑热能通风空调,2001年第6期,8~13
NGLC 2004-2010.National Geological Library of China All Rights Reserved.
Add:29 Xueyuan Rd,Haidian District,Beijing,PRC. Mail Add: 8324 mailbox 100083
For exchange or info please contact us via email.